Please use this identifier to cite or link to this item: http://dx.doi.org/10.25673/36852
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dc.contributor.authorLiebing, Phil-
dc.contributor.authorHarmgarth, Nicole-
dc.contributor.authorZörner, Florian-
dc.contributor.authorEngelhardt, Felix-
dc.contributor.authorHilfert, Liane-
dc.contributor.authorBusse, Sabine-
dc.contributor.authorEdelmann, Frank T.-
dc.date.accessioned2021-06-07T10:03:48Z-
dc.date.available2021-06-07T10:03:48Z-
dc.date.issued2019-
dc.date.submitted2019-
dc.identifier.urihttps://opendata.uni-halle.de//handle/1981185920/37084-
dc.identifier.urihttp://dx.doi.org/10.25673/36852-
dc.description.abstractTwo new main group element carboranylamidinates were synthesized using a bottom-up approach starting from o-carborane, ortho-C2B10H12 (1, = 1,2-dicarba-closo-dodecaborane). The first divalent germanium carboranylamidinate, GeCl[HLCy] (3, [HLCy]− = [o-C2B10H10C(NCy)(NHCy)]−, Cy = cyclohexyl), was synthesized by treatment of GeCl2(dioxane) with 1 equiv. of in situ-prepared Li[HLCy] (2a) in THF and isolated in 47% yield. In a similar manner, the first antimony(III) carboranylamidinate, SbCl2[HLiPr] (4, [HLiPr]− = [o-C2B10H10C(NiPr)(NHiPr)]−), was obtained from a reaction of SbCl3 with 1 equiv. of Li[HLiPr] in THF (56% yield). The title compounds were fully characterized by analytical and spectroscopic methods as well as single-crystal X-ray diffraction. Both compounds 3 and 4 are monomeric species in the solid state, and the molecular geometries are governed by a stereo-active lone pair at the metal centers.eng
dc.description.sponsorshipDFG-Publikationsfonds 2019-
dc.language.isoeng-
dc.relation.ispartofhttp://www.mdpi.com/journal/inorganics-
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/-
dc.subjectBoroneng
dc.subjectCarboraneeng
dc.subjectCarboranylamidinateeng
dc.subjectGermaniumeng
dc.subjectCrystal structureeng
dc.subject.ddc660-
dc.titleSynthesis and structural characterization of two new main group element carboranylamidinateseng
dc.typeArticle-
dc.identifier.urnurn:nbn:de:gbv:ma9:1-1981185920-370849-
local.versionTypepublishedVersion-
local.bibliographicCitation.journaltitleInorganics-
local.bibliographicCitation.volume7-
local.bibliographicCitation.issue3-
local.bibliographicCitation.pagestart1-
local.bibliographicCitation.pageend41-
local.bibliographicCitation.publishernameMDPI-
local.bibliographicCitation.publisherplaceBasel-
local.bibliographicCitation.doi10.3390/inorganics7030041-
local.openaccesstrue-
dc.identifier.ppn1681894130-
local.bibliographicCitation.year2019-
cbs.sru.importDate2021-06-07T09:57:28Z-
local.bibliographicCitationEnthalten in Inorganics - Basel : MDPI, 2013-
local.accessrights.dnbfree-
Appears in Collections:Fakultät für Verfahrens- und Systemtechnik (OA)

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