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http://dx.doi.org/10.25673/38526
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Feofanov, Mikhail | - |
dc.contributor.author | Akhmetov, Vladimir | - |
dc.contributor.author | Amsharov, Konstantin | - |
dc.date.accessioned | 2021-09-29T10:06:13Z | - |
dc.date.available | 2021-09-29T10:06:13Z | - |
dc.date.issued | 2020 | - |
dc.identifier.uri | https://opendata.uni-halle.de//handle/1981185920/38772 | - |
dc.identifier.uri | http://dx.doi.org/10.25673/38526 | - |
dc.description.abstract | Alumina-mediated C-F activation (AmCFA) is an established method to generate incipient phenyl cation (IPC) through polarization of C(aryl)-F bonds. Herein, it is reported that AmCFA can be used to induce intramolecular arylation of aryl alkynes containing one, two, and three triple bonds. During the reaction, a single formally eliminated hydrogen fluoride (HF) leads to the formation of two, three, and four C-C bonds, respectively. Thus, the transformation gives rapid access to π-extension and serves as an interesting example of solid-state rational domino annulation enabling the bottom-up construction of nanographenes. | eng |
dc.description.sponsorship | Publikationsfonds MLU | - |
dc.language.iso | eng | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.subject.ddc | 546 | - |
dc.title | Annulation cascade of aryl alkynes induced by alumina-mediated C-F bond activation | eng |
dc.type | Article | - |
local.versionType | publishedVersion | - |
local.bibliographicCitation.journaltitle | Physica status solidi / B | - |
local.bibliographicCitation.volume | 257 | - |
local.bibliographicCitation.issue | 12 | - |
local.bibliographicCitation.publishername | Wiley-VCH | - |
local.bibliographicCitation.publisherplace | Weinheim | - |
local.bibliographicCitation.doi | 10.1002/pssb.202000296 | - |
local.openaccess | true | - |
local.accessrights.dnb | free | - |
Enthalten in den Sammlungen: | Open Access Publikationen der MLU |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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pssb.202000296.pdf | 329.85 kB | Adobe PDF | ![]() Öffnen/Anzeigen |