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DC Field | Value | Language |
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dc.contributor.author | Liebing, Phil | - |
dc.contributor.author | Merzweiler, Kurt | - |
dc.date.accessioned | 2022-05-23T06:31:54Z | - |
dc.date.available | 2022-05-23T06:31:54Z | - |
dc.date.issued | 2022 | - |
dc.identifier.uri | https://opendata.uni-halle.de//handle/1981185920/87915 | - |
dc.identifier.uri | http://dx.doi.org/10.25673/85962 | - |
dc.description.abstract | The thioether-functionalized aminosilanes Me2Si(NH-C6H4-2-SR)2 (R=Ph, Me) were lithiated with n-BuLi and subsequently allowed to react with CuCl in the presence of PMe3. In the case of Me2Si(NH-C6H4-2-SPh)2, the dinuclear complex [Cu2{Me2Si(NC6H4-2-SPh)2}(PMe3)2] was isolated. In [Cu2{Me2Si(NC6H4-2-SPh)2}(PMe3)2] the copper atoms adopt a distorted trigonal-planar coordination (Cu−N: 191.2(2) pm, Cu−P: 216.3(1) pm, Cu−S: 244.4(1) pm). The reaction of Li2Me2Si(N-C6H4-2-SMe)2 with CuCl in the presence of PMe3 led to rearrangement processes from which the ionic cluster compound [Cu(PMe3)4][Cu5{Me2Si(N-C6H4-2-S)(N-C6H4-2-S−Me)}2(PMe3)2] was isolated in low yield. | eng |
dc.description.sponsorship | Publikationsfonds MLU | - |
dc.language.iso | eng | - |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | - |
dc.subject.ddc | 540 | - |
dc.title | Copper(I) complexes with thioether-functionalized Silylamido ligands | eng |
dc.type | Article | - |
local.versionType | publishedVersion | - |
local.bibliographicCitation.journaltitle | Zeitschrift für anorganische und allgemeine Chemie | - |
local.bibliographicCitation.volume | 648 | - |
local.bibliographicCitation.issue | 4 | - |
local.bibliographicCitation.publishername | Wiley-VCH | - |
local.bibliographicCitation.publisherplace | Weinheim | - |
local.bibliographicCitation.doi | 10.1002/zaac.202100339 | - |
local.openaccess | true | - |
local.accessrights.dnb | free | - |
Appears in Collections: | Open Access Publikationen der MLU |
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File | Description | Size | Format | |
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Zeitschrift anorg allge chemie - 2022 - Liebing - Copper I Complexes with Thioether‐Functionalized Silylamido Ligands.pdf | 689.77 kB | Adobe PDF | View/Open |