Please use this identifier to cite or link to this item:
http://dx.doi.org/10.25673/85324| Title: | Kinetic modeling of rhodium‐catalyzed reductive amination of undecanal in different solvent systems |
| Author(s): | Kirschtowski, Sabine Kadar, Christof Seidel-Morgenstern, Andreas  Hamel, Christof |
| Issue Date: | 2020 |
| Type: | Article |
| Language: | English |
| URN: | urn:nbn:de:gbv:ma9:1-1981185920-872761 |
| Subjects: | Homogenous catalysis Kinetic modeling Reductive amination Rhodium catalysis |
| Abstract: | The homogenously rhodium-catalyzed reductive amination of 1-undecanal was performed in two different thermomorphic solvent systems with the ligand Xantphos. The influences of partial pressure, temperature, methanol and catalyst concentration on the reaction were investigated. Based on a network analysis a kinetic model was derived and successfully parametrized for all studied solvent systems. Simulation results were found to be in good agreement with the experiments and allow a further process development and optimization. |
| URI: | https://opendata.uni-halle.de//handle/1981185920/87276 http://dx.doi.org/10.25673/85324 |
| Open Access: |  Open access publication |
| License: |  (CC BY-NC-ND 4.0) Creative Commons Attribution NonCommercial NoDerivatives 4.0 |
| Sponsor/Funder: | Projekt DEAL 2020 |
| Journal Title: | Chemie - Ingenieur - Technik |
| Publisher: | Wiley-VCH Verl. |
| Publisher Place: | Weinheim |
| Volume: | 92 |
| Issue: | 5 |
| Original Publication: | 10.1002/cite.201900135 |
| Page Start: | 582 |
| Page End: | 588 |
| Appears in Collections: | Fakultät für Verfahrens- und Systemtechnik (OA) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Kirschtowski et al._Kinetic Modeling of rhodium_2020.pdf | Zweitveröffentlichung | 234.57 kB | Adobe PDF |  View/Open |