Bitte benutzen Sie diese Kennung, um auf die Ressource zu verweisen:
http://dx.doi.org/10.25673/111363
Langanzeige der Metadaten
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Liebing, Phil | - |
dc.contributor.author | Schatz, Philipp | - |
dc.contributor.author | Merzweiler, Kurt | - |
dc.date.accessioned | 2023-10-24T06:10:16Z | - |
dc.date.available | 2023-10-24T06:10:16Z | - |
dc.date.issued | 2023 | - |
dc.identifier.uri | https://opendata.uni-halle.de//handle/1981185920/113317 | - |
dc.identifier.uri | http://dx.doi.org/10.25673/111363 | - |
dc.description.abstract | A series of three lithium silylamides Li2Me2Si(NC6H4-2-SR)2 (R=Me, Ph, tBu) were prepared from the reaction of the corresponding silylamines Me2Si(NH-C6H4-2-SR)2 with n-butyl lithium. X-ray single crystal structure analyses revealed the formation of dimers [Li4{Me2Si(NC6H4-2-SR)2}2] with Si2N4Li4 hetero-adamantane cores. Recrystallisation of [Li4{Me2Si(NC6H4-2-SMe)2}2] and [Li4{Me2Si(NC6H4-2-SPh)2}2] from diethyl ether led to the formation of the adducts [Li4(Et2O)2{Me2Si(NC6H4-2-SMe)2}2] and [Li4(Et2O){Me2Si(NC6H4-2-SPh)2}2]. In the case of the SMe derivative the addition of two diethyl ether molecules led to a rearrangement of the Si2N4Li4 core to give a double decker structure and in contrast the hetero adamantane structure is retained in the diethyl ether adduct of the SPh derivative. | eng |
dc.language.iso | eng | - |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.subject.ddc | 540 | - |
dc.title | Synthesis and crystal structures of three thioether functionalized lithium silylamides | eng |
dc.type | Article | - |
local.versionType | publishedVersion | - |
local.bibliographicCitation.journaltitle | Zeitschrift für anorganische und allgemeine Chemie | - |
local.bibliographicCitation.volume | 649 | - |
local.bibliographicCitation.issue | 19 | - |
local.bibliographicCitation.pagestart | 1 | - |
local.bibliographicCitation.pageend | 7 | - |
local.bibliographicCitation.publishername | Wiley-VCH | - |
local.bibliographicCitation.publisherplace | Weinheim | - |
local.bibliographicCitation.doi | 10.1002/zaac.202300100 | - |
local.openaccess | true | - |
dc.identifier.ppn | 1859198945 | - |
cbs.publication.displayform | 2023 | - |
local.bibliographicCitation.year | 2023 | - |
cbs.sru.importDate | 2023-10-24T06:09:24Z | - |
local.bibliographicCitation | Enthalten in Zeitschrift für anorganische und allgemeine Chemie - Weinheim : Wiley-VCH, 1892 | - |
local.accessrights.dnb | free | - |
Enthalten in den Sammlungen: | Open Access Publikationen der MLU |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
---|---|---|---|---|
Zeitschrift anorg allge chemie - 2023 - Liebing - Synthesis and Crystal Structures of Three Thioether Functionalized.pdf | 1.33 MB | Adobe PDF | ![]() Öffnen/Anzeigen |