Please use this identifier to cite or link to this item:
http://dx.doi.org/10.25673/78162
Title: | cyclo-Tetrakis(μ-2,4,6-trimethylphenyl-κC1:κC1)bis(trimethylphosphane)-1κP,3κP-tetracopper(I) |
Author(s): | Liebing, Phil Merzweiler, Kurt |
Issue Date: | 2021 |
Type: | Article |
Language: | English |
Abstract: | The title compound, [Cu4(C9H11)4(C3H9P)2] or [Cu4(Mes)4(PMe3)2] (Mes = 2,4,6-trimethylphenyl), was synthesized from copper(I) mesityl and trimethylphosphane in THF as solvent. The molecular structure of the complex has C2 symmetry and consists of four copper(I) atoms bridged by four μ-mesityl groups, giving an eight-membered puckered {Cu4C4} ring. Additionally, two copper(I) atoms at opposite corners of the Cu4 rhomb are each linked to a terminal PMe3 ligand. The PMe3-bearing copper(I) atoms exhibit a distorted trigonal–planar coordination mode whereas the remaining Cu atoms linked to two mesityl groups are nearly linearly coordinated. |
URI: | https://opendata.uni-halle.de//handle/1981185920/80116 http://dx.doi.org/10.25673/78162 |
Open Access: | Open access publication |
License: | (CC BY 4.0) Creative Commons Attribution 4.0 |
Sponsor/Funder: | Publikationsfonds MLU |
Journal Title: | IUCrData |
Publisher: | IUCr |
Publisher Place: | Chester |
Volume: | 6 |
Original Publication: | 10.1107/S2414314621005940 |
Appears in Collections: | Open Access Publikationen der MLU |
Files in This Item:
File | Description | Size | Format | |
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wm4146.pdf | 578.11 kB | Adobe PDF | View/Open |