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http://dx.doi.org/10.25673/103447
Titel: | A new rapid and specific iodination reagent for phenolic compounds |
Autor(en): | Hauenschild, Till![]() Hinderberger, Dariush ![]() |
Erscheinungsdatum: | 2023 |
Art: | Artikel |
Sprache: | Englisch |
Zusammenfassung: | A new rapid iodination reagent, N1,N3,N5-tris[(2,4,6-trimethylpyridine)iodo(I)]-2,4,6-triphenyl-s-triazine trihexafluorophosphate, was synthesized in a modification of the established synthesis of 2,4,6-triiodo-3,5-dimethylphenol in the presence of bis(2,4,6-trimethylpyridine)iodo(I) hexafluorophosphate and used for the precise post-modification of mono- and trisubstituted phenyl compounds. We performed triple iodinations with our new phenyl-based compounds as a proof of principle of selected types of phenols, ß-sympatholytic agents and their spin-labeled derivatives, which can be employed in electron paramagnetic resonance (EPR) spectroscopy. The new rapid iodination reagent can be employed with high reactivity and regioselectivity. |
URI: | https://opendata.uni-halle.de//handle/1981185920/105401 http://dx.doi.org/10.25673/103447 |
Open-Access: | ![]() |
Nutzungslizenz: | ![]() |
Journal Titel: | Organics |
Verlag: | MDPI |
Verlagsort: | Basel, Switzerland |
Band: | 4 |
Heft: | 2 |
Originalveröffentlichung: | 10.3390/org4020011 |
Seitenanfang: | 137 |
Seitenende: | 145 |
Enthalten in den Sammlungen: | Open Access Publikationen der MLU |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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organics-04-00011-v3.pdf | 3.22 MB | Adobe PDF | ![]() Öffnen/Anzeigen |