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http://dx.doi.org/10.25673/85962| Title: | Copper(I) complexes with thioether-functionalized Silylamido ligands |
| Author(s): | Liebing, Phil Merzweiler, Kurt |
| Issue Date: | 2022 |
| Type: | Article |
| Language: | English |
| Abstract: | The thioether-functionalized aminosilanes Me2Si(NH-C6H4-2-SR)2 (R=Ph, Me) were lithiated with n-BuLi and subsequently allowed to react with CuCl in the presence of PMe3. In the case of Me2Si(NH-C6H4-2-SPh)2, the dinuclear complex [Cu2{Me2Si(NC6H4-2-SPh)2}(PMe3)2] was isolated. In [Cu2{Me2Si(NC6H4-2-SPh)2}(PMe3)2] the copper atoms adopt a distorted trigonal-planar coordination (Cu−N: 191.2(2) pm, Cu−P: 216.3(1) pm, Cu−S: 244.4(1) pm). The reaction of Li2Me2Si(N-C6H4-2-SMe)2 with CuCl in the presence of PMe3 led to rearrangement processes from which the ionic cluster compound [Cu(PMe3)4][Cu5{Me2Si(N-C6H4-2-S)(N-C6H4-2-S−Me)}2(PMe3)2] was isolated in low yield. |
| URI: | https://opendata.uni-halle.de//handle/1981185920/87915 http://dx.doi.org/10.25673/85962 |
| Open Access: |  Open access publication |
| License: |  (CC BY-NC 4.0) Creative Commons Attribution NonCommercial 4.0 |
| Sponsor/Funder: | Publikationsfonds MLU |
| Journal Title: | Zeitschrift für anorganische und allgemeine Chemie |
| Publisher: | Wiley-VCH |
| Publisher Place: | Weinheim |
| Volume: | 648 |
| Issue: | 4 |
| Original Publication: | 10.1002/zaac.202100339 |
| Appears in Collections: | Open Access Publikationen der MLU |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Zeitschrift anorg allge chemie - 2022 - Liebing - Copper I Complexes with Thioether‐Functionalized Silylamido Ligands.pdf | 689.77 kB | Adobe PDF |  View/Open |